Marvelous self-assembly of hierarchically nanostructured porous zirconium phosphate solid acids with high thermal stability

A hierarchical structure of thermally stable macroporous zirconium phosphate solid acids with supermicroporous walls was prepared by a simple self-assembly process from the precursors of zirconium propoxide and orthophosphoric acid solution. The macroporous structures are uniform with the diameters ranging from 300 to 800 nm, one-dimensional channel-like. The effect of surfactant Brij 56 on the formation of macroporous structures has been studied. The frameworks of the synthesized hierarchical zirconium phosphates are amorphous with Zr–O–P bonding, exhibiting remarkably high thermal stability (at least 800 °C), on the basis of the X-ray diffraction (XRD), N₂ adsorption, X-ray photoelectron spectroscopy (XPS) analysis, Fourier transform infrared (FT-IR) and ³¹P nuclear magnetic resonance (NMR) spectra. Larger quantities of Zr–OH and P–OH groups are observed besides surface hydroxyl groups, suggesting the presence of acidity and the possibility of surface functionalization for practical applications including catalysis. The macroporous zirconium phosphates with hierarchical structures could also be the potential and efficient catalyst supports for the design of the structured catalysts and reactors.     

Influence of torsion deformation on microstructure of cold-drawn pearlitic steel wire

A comparative microstructural analyse of cold-drawn pearlitic steel wires in as-drawn and after an additional torsion deformation states is presented in this paper. During torsion the temperature of the wire increases to attain 90 °C. Then the microstructure of wires is the result of different events effects, as initial drawing, temperature increase and torsion deformation. Individually or in association, both events influence the stress level and nature in ferrite and cementite lamellae, modify the kinetic of cementite decomposition and change the dislocation mobility in cementite and ferrite. Carbon atoms migration from cementite to ferrite is affected by these thermomechanical treatments inducing a modification of dislocation pinning by carbon atoms and lamellae interfaces. The phases’ determination and quantification, associated with the carbon content variation in each phase was investigated by Mössbauer spectroscopy. The evolution of the pearlitic steel wires microstructure will be discussed point-by-point, as a function of applied deformation nature.     

Effects of landscape structure on vegetation and some animal groups after agriculture abandonment

This research was carried out on the montane belt of a south-exposed watershed in the Intermediary Alps which have been hit by agriculture abandonment. The aim of the study was to study the relationships between vegetation, landscape mosaic, and two kinds of animals using this space at different scales: roe deer (Capreolus capreolus) and earthworms (lumbricids). Landscape dynamics (post-cultural recolonisation) and landscape structure have been approached by means of the Arc/Info geographical information system (GIS). Several methods used to study on one hand roe deer distribution, and, on the other, earthworm abundance and diversity are developed. Of these, in particular, GIS processing is used to sample earthworms according to vegetation dynamics, and roe deer distribution is related to landscape heterogeneity. Earthworms are more abundant and diversified in the key steps of vegetation dynamics. These lumbricids can be considered as functional indicators of these dynamics. Results also demonstrate that both the vegetation type and the landscape heterogeneity have a direct influence on the use of the space by the roe deer. They show themselves to be structural indicators of the landscape.     

Optical modeling of organic solar cells based on CuPc and C60

We have investigated the influence of the poly(3,4-ethylenedioxythiophene)-blend-poly(styrene-sulfonate) (PEDOT:PSS) layer on the short-circuit current density (J(sc)) of single planar heterojunction organic solar cells based on a copper phthalocyanine (CuPc)-buckminsterfullerene (C(60)) active layer. Complete optical and electrical modeling of the cell has been performed taking into account optical interferences and exciton diffusion. Comparison of experimental and simulated external quantum efficiency has allowed us to estimate the exciton diffusion length to be 37 nm for the CuPc and 19 nm for the C(60). The dependence of short-circuit current densities versus the thickness of the PEDOT:PSS layer is analyzed and compared with experimental data. It is found that the variation in short-circuit current densities could be explained by optical interferences.     

Differences in the aerosolization behavior of microorganisms as revealed through their transport by biogas

The aerosol microbial diversity of biogas was analyzed in order to examine the aerosolization behavior of microorganisms. Six biogas samples were analyzed: five from mesophilic and thermophilic anaerobic digestors treating different wastes, and one from landfill. Epifluorescent microscopic counts reveal that with 10(6) Prokarya m(-3), only one per one thousand billion were aerosolized from the digestor sludges to the biogas. SSU (Small Sub Unit) ribosomal fingerprinting (Single Strand Conformation Polymorphism) shows that microbial communities in the biogas were not just a rough copy of anaerobic digestor microbial communities and underlines that all microorganisms are not equally convoyed by biogas. To assess the difference occurring in aerosolization, 675 biogas-borne SSU ribosomal DNA were analyzed and compared to published anaerobic digestor microbial diversity. Results show that microorganisms belonging to Archaea, Deltaproteobacteria, Spirochaetes, Thermotogae, Chloroflexi phyla and sulfate-reducing groups were non-aerosolized whereas microorganisms belonging to Alphaproteobacteria, Betaproteobacteria, Gammaproteobacteria, TM7 phyla as well as strictly aerobic and occasionally pathogenic species presented high levels of aerosolization. Finally, microorganisms belonging to Actinobacteria, Firmicutes and Bacteroidetes phyla represent passively-aerosolized microorganisms with similar frequencies in biogas-borne and anaerobic digestor microbial communities.     

Measurement of enzymatic activity and specificity of human and avian influenza neuraminidases from whole virus by glycoarray and MALDI-TOF mass spectrometry

Influenza neuraminidases hydrolyze the ketosidic linkage between N-acetylneuraminic acid and its adjacent galactose residue in sialosides. This enzyme is a tetrameric protein that plays a critical role in the release of progeny virions. Several methods have been described for the determination of neuraminidase activity, usually based on colorimetric, fluorescent, or chemiluminescent detection. However, only a few of these tests allow discrimination of the sialyl-linkage specificity (i.e., α2-3- versus α2-6-linked sialyllactosides) of the neuraminidase. Herein we report a glycoarray-based assay and a MALDI-TOF study for assessing the activity and specificity of two influenza neuraminidases on whole viruses. The human A(H3N2) and avian A(H5N2) neuraminidase activities were investigated. The results from both approaches demonstrated that α2-3 sialyllactoside was a better substrate than α2-6 sialyllactoside for both viruses and that H5N2 virus had a lower hydrolytic activity than H3N2.     

Stability of hydrogen incorporated in ZnO nanowires by plasma treatment

The stability of hydrogen in ZnO is studied using hydrogenated nanowires by plasma treatment. Enhanced near band edge UV emission and reduced defect level green emission is observed after hydrogen plasma treatment. Through thermal stability tests, this effect is found to be stable at room temperature and nearly stable up to ~500 K, but begins to deteriorate at higher temperature. The study of the irradiation stability of the hydrogen in ZnO nanowires shows that the hydrogen is stable under an electron beam with an accelerating voltage lower than 5 kV, but is not stable under 10 kV or under an intensive laser beam. The results could benefit the further understanding of the role of hydrogen in ZnO and light-emitting devices based on hydrogenated ZnO.